Hi Adam, thanks for your very helpful response, I am working hard on this stuff and hopefully learning but quite a steep curve.
I'm not sure what order I ran the processes in my original post, I have since written down a basic workflow which I will adapt but didn't do this for the first couple of attempts.
The image is RBG only, I haven't got as far as adding in Lum and Ha yet (next on my list), so HDRMT would have been applied to the RGB as a whole.
I think I only used SCNR as a final step to remove a green cast.
ColourCal. I used White and Background Previews.
The white was made up of 7 preview "slices" so that I covered the whole of M31 (being on a diagonal it was the only way I could think to do it) and then aggregated them with the Preview aggregation script (whatever its called). Lower limit set just above background reading, which was high - background was something around .0025 where I expected around .007. Upper limit left at default.
Background. Upper limit .01, lower limit default.
Structure detection off.
I checked both reference graphs and thought they looked ok - checked against the Harry PI video tutorial.
If there is anything obviously wrong with the above do let me know.
I have read about the photometric colour calibration but not had chance to try it yet - sounds excellent.
The nicest surprise I have found to date is Blink and the Image analysis script (sorry I don't have PI on this laptop, one of the limitations of the trial, and cant remember the name). Using these I identified that a significant number of lights were sub standard. The mist came in one night and I didn't notice as I was monitoring from indoors!!!! Anyway, they are a major incentive for me to purchase PI in themselves.
I used these today to analyse the results of an experiment with calibration frames. I used various combinations of Darks, Flats, Dark Flats and Bias in APP pre-processing. I usually use all 4 types but my trial showed there was no difference that I could detect in quality whether I used all four or just flats/dark flats with either Darks or Bias. The one without Bias looked "milky" in Blink compared to the others and had lower star count but identical noise and FWHM, but when I processed each stack I couldn't differentiate visually. I suspect the milkiness was removed by the LP wipe (I used Star Tools for a quick process as it only takes a couple of minutes per stack). Not scientific but interesting.
Thanks again for your detailed reply.
Jon