Scott,
Like the others that have replied, I really encourage you to stick with it. I come from a CCDStack and Photoshop background and while it involves learning new skills, PI more than pays you back for that effort. From my perspective its what you touched on in one of your comments, namely the ability in PI to "get under the hood" and actually understand what the program is doing to improve your images. Combine that with the fact that you are actually working with the data and not just painting on layers, makes this, IMHO, the premier astrophotgraphy package out there.
If it helps at all, I have just posted my Cribsheet which sets out my workflow as well as any number of tool tips that may prove handy. It is designed for my CCD monochrome workflow, but much of it is translatable to a DSLR.
On a couple of your questions, re synlums, I have had some lengthy discussions with Juan, the primary PI developer, and others here on the philosophy of using luminosity images as a part of an LRGB set or whether to build a synthetic lum from the RGB data. Based on the recommendations of others I have just switched my imaging to use unbidded RGB's that I will use to build a synlum (really had to sweat that one but everything they said just makes sense). In fact, before I went on vacation a couple of weeks ago, I took two nights of RGB images of NGC891 that are just waiting for me to start processing as my first synlum experiment. As soon I am over my jetlag, I will be turning my full attention to the set (probably this weekend) and will report on my results.
On the question of using the BPP, I have not done so to date, partly because I am old school and partly because of what I said above, namely that I want to control each step. For example, I run a whole series of ImageIntegrations using different sigma settings for each color channel (and, to date, for my Lums as well), then compare the results using the SubFrameSelector script. I would not be able to exercise that same level of comtrol if I used BPP.
Hope that helps,
Jim