Hi Carlos,
is there anything to the "pixinsight warning" in the console I posted?
You can safely ignore that "com.apple.wifi.scan entitlement" console error message. I see it also on our working OS X machines. It causes no problems and has nothing to do with the issues you are having.
Slight improvement during the initial launch, although the script loading step still takes longer than it should.
As you can see on the small video I uploaded yesterday, we cannot reproduce this. Running the application and loading modules and scripts is very fast. The machine where I captured the video has tons of large applications installed, including the entire Xcode suite, music and video production software with lots of plugins, VMware Fusion with 5 virtual machines, Wolfram Mathematica (7 GB), etc. So it is not a 'free' machine by any means.
Quitting also a very slight improvement but still tends to linger for a bit before the app highlight disappears.
Quitting PixInsight is also quite fast on OS X. However, bear in mind that if you have many modified images with complex processing histories when you close the application, PixInsight has to remove many temporary swap files, sometimes involving many gigabytes of disk storage. This task may take a while, depending mainly on your hard disk and processor speed.