Although Juan has mentioned possibly adding GPU acceleration in the future, to date PI does not use it. As such, as between the two I would spend the money on a faster CPU. But your biggest bang for the buck might be to add an SSD and have your system run off of that instead of a traditional hard drive. You can always get a big cheap hard drive as your D: drive to store all the data, but a solid state drive as your C: drive makes a huge difference. The other place to spend money is on memory. Get a minimum of 16Gb and 32Gb if you can afford it, then add a ramdisk.
Best,
Jim