Hi Andy :)
The first thing that you should know about PixInsight's paradigma is that you have control over almost everything. That means, we sacrifice user friendly interfases with advanced controls, so you may fine tune the parameters, and reach eventually better results. Regarding your wavelets doubt, first you must know what a wavelets are: it is just a decomposition of the image into several layers, wich each one of them contains details of the image between a defined range of scales. In simple words, to give an example, with wavelets you may split an image of a galaxy into 3 layers, were the first one contains stars and other high frecuency features, the second shows the spiral arms, and the last one gives you the large scale form of the galaxy. Now, you may work with each of the scale components individually.
After that introduction, our A Trous Wavelets process allows you to change the way all the scales are merged again. If you disable a layer, you blur the image, becouse some details are lost. If you increase the bias, you increase the contrast of that layer, and then you are sharpening those scales. It is a matter of trial and error to find out the best values for your image.
Now, regarding documentation... We know we lack a complete documentation, and many tutorials, specially for people who is not familiar with image processing techniques. Meanwhile, I recommend you to read our online tutorials, and just play with your images to see what happens. Also you should read PixInsight LE's official documentation, wich may be a good introduction to many processes on our standard edition.
Regarding printed books, take a look at "Digital Image Processing" by Gutierrez (it was an spanish name, but it writen in inglish). It is general book, that cover all the basis, applied to almost every field of today's image processing. Another good book, but less "formal", and more oriented to users than to teach the basics, is "The Handbook of Astronomical Image Processing" by Richard Berry and James Burnell. There are many other books, more oriented to astronomy, but they ussually goes around Photoshop, and you'll quickly surpass their level. Just tell you tricks, but not a good knowlegde on what you are doing.
Finally, of course, you have this forum. We'll happilly answer your questions. Just remember to search the answer in older posts, so you don't repeat topics.