i wasn't able to get this to directly solve with PCC, but if you run the ImageSolver script and set the resolution (pixel scale) to 1, it will solve. with the WCS coordinates now in the image, PCC will run OK without making any changes to the PCC interface.
so, something is wrong with the image metadata - this doesn't look like a 400mm telescope + 4.6um pixels; the field of view is too small for that. what kind of camera are you using?
also i would do DBE to this image before runnign PCC, the gradient is pretty bad.
rob