What's the output of ldd PixInsight?
PixInsight should be run via the script it ships with (at least on FreeBSD, I'm assuming this is the case on Linux as well): ./PixInsight.sh
This script sets up a few environment variables, most notably, in this instance, are the paths for your system's loader to find the shared libraries for the binary you're trying to run e.g. LD_LIBRARY_PATH and friends. The script sets up these paths to PixInsight's local libraries.
YMMV: PixInsight doesn't work on recent FreeBSD, for example, because it's not binary compatible with system libc, and it raises a sigabort and dumps core.